Watch the odd-numbered ones first, then the evens.
All jokes aside: my preference is the release order, though the Machete order seems like it would be a good plan (feel free to include Rogue One, it is superb in my book).
Aside from Pussy Galore, another favorite inappropriate Bond moment I enjoy is from The Man with the Golden Gun.
Bond approaches an Asian woman skinny dipping in a pool and asks her for her name.
That reminds me of a scene from Jean-Luc Godard's La Chinoise, where some members of a Maoist group call others "conformists" or something to that effect because they hold different views on the finer details of communism/socialism.
High fantasy and futuristic sci-fi. I will accept and love this bastardization.